{μ-N,N,N′,N′-Tetrakis[(diphenylphosphanyl)methyl]benzene-1,4-diamine}bis[(2,2′-bipyridyl)copper(I)] bis(tetrafluoridoborate)
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چکیده
In the title compound, [Cu(2)(C(10)H(8)N(2))(2)(C(58)H(52)N(2)P(4))](BF(4))(2), the dinuclear cation lies on an inversion centre. The Cu(I) atom is coordinated by two N atoms from a 2,2'-bipyridine ligand and two P atoms from an N,N,N',N'-tetra-kis-[(diphenyl-phos-phan-yl)meth-yl]benzene-1,4-diamine ligand in a distorted tetra-hedral geometry. In the crystal, inter-molecular C-H⋯F hydrogen bonds link the ions into layers parallel to [[Formula: see text]01]. π-π inter-actions [centroid-centroid distance = 3.668 (4) Å] are also observed. One F atom of the anion is disordered over two orientations with a refined occupancy ratio of 0.675 (13):0.325 (13).
منابع مشابه
{μ-trans-N,N′-Bis[(diphenylphosphanyl)methyl]benzene-1,4-diamine-κ2 P:P′}bis{(acetonitrile-κN)[dipyrido[3,2-a:2′,3′-c]phenazine-κ2 N 4,N 5]copper(I)} bis(tetrafluoridoborate)
In the centrosymmetric dinuclear title compound, [Cu(2)(C(2)H(3)N)(2)(C(18)H(10)N(4))(2)(C(32)H(30)N(2)P(2))](BF(4))(2), the Cu(I) centre is coordinated by two N atoms from a dipyridophenazine ligand, one P atom from an N,N'-bis-[(diphenyl-phosphan-yl)meth-yl]benzene-1,4-diamine (bpbda) ligand, and one N atom from an acetonitrile mol-ecule in a distorted tetra-hedral geometry. The bpbda ligand,...
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The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N'-bis-(diphenyl-phosphinometh-yl)ben-zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin-ated by one chelating 2,2'-bipyridine ligand, giving a distorted trigonal coordination environment.
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